Molybdenum is a Group 6 chemical element with the symbol Mo and atomic number 42. The name is from Neo-Latin Molybdaenum, from Ancient Greek, meaning lead, itself proposed as a loanword from Anatolian Luvian and Lydian languages, since its ores were confused with lead ores. The free element, which is a silvery metal, has the sixth-highest melting point of any element. It readily forms hard, stable carbides, and for this reason it is often used in high-strength steel alloys. Molybdenum does not occur as a free metal on Earth, but rather in various oxidation states in minerals. Industrially, molybdenum compounds are used in high-pressure and high-temperature applications, as pigments and catalysts.
Molybdenum minerals accept continued been known, but the aspect was "discovered" (in the faculty of appropriate it as a new article from the mineral salts of added metals) in 1778 by Carl Wilhelm Scheele. The metal was aboriginal abandoned in 1781 by Peter Jacob Hjelm.
Most molybdenum compounds accept low solubility in water, but the molybdate ion MoO42− is acrid and forms if molybdenum-containing minerals are in acquaintance with oxygen and water.
Molybdenum-containing enzymes are acclimated as catalysts by some bacilli to breach the actinic band in atmospheric atomic nitrogen, acceptance biological nitrogen fixation. At atomic 50 molybdenum-containing enzymes are now accepted in bacilli and animals, admitting alone the bacterial and cyanobacterial enzymes are complex in nitrogen fixation. Owing to the assorted functions of the butt of the enzymes, molybdenum is a appropriate aspect for activity in college bacilli (eukaryotes), admitting not in all bacteria.
Applications
Alloys
The adeptness of molybdenum to bear acute temperatures after decidedly accretion or abatement makes it advantageous in applications that absorb acute heat, including the accomplish of armour, aircraft parts, electrical contacts, automated motors and filaments.
Most high-strength animate alloys (example 41xx steels) accommodate 0.25% to 8% molybdenum. Despite such baby portions, added than 43,000 tonnes of molybdenum are acclimated as an alloying abettor anniversary year in stainless steels, apparatus steels, casting band and high-temperature superalloys.
Molybdenum is aswell acclimated in animate alloys for its top bane attrition and weldability. Molybdenum contributes added bane attrition to "chrome-moly" type-300 stainless steels (high-chromium steels that are corrosion-resistant already due to their chromium content) and abnormally so in the alleged superaustenitic stainless steels (such as admixture AL-6XN). Molybdenum acts by accretion filigree strain, appropriately accretion the activity appropriate to deliquesce out adamant atoms from the surface.
Because of its lower body and added abiding price, molybdenum is sometimes acclimated instead of tungsten. An archetype is the 'M' alternation of accelerated steels such as M2, M4 and M42 as barter for the 'T' animate alternation which accommodate tungsten. Molybdenum can be implemented both as an alloying abettor and as a flame-resistant blanket for added metals. Although its melting point is 2,623 °C (4,753 °F), molybdenum rapidly oxidizes at temperatures aloft 760 °C (1,400 °F) authoritative it better-suited for use in exhaustion environments.
TZM (Mo (~99%), Ti (~0.5%), Zr (~0.08%) and some C) is a corrosion-resisting molybdenum superalloy that resists aqueous fluoride salts at temperatures aloft 1300C. It has about alert the backbone of authentic Mo, and is added adaptable and added weldable, yet in tests it resisted bane of a accepted eutectic alkali (FLiBe) and alkali abasement acclimated in aqueous alkali reactors for 1100 hours with so little bane that it was difficult to measure.
Other molybdenum-based alloys which do not accommodate adamant accept alone bound applications. For example, because of the bane attrition adjoin aqueous zinc, both authentic molybdenum and the molybdenum/tungsten admixture (70%/30%) are acclimated for piping, stirrers and pump impellers which appear into acquaintance with aqueous zinc.
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