Tuesday 14 February 2012

What is Cobalt nitrate?

Cobalt nitrate is the inorganic cobalt(II) salt of nitric acid, often with various amounts of water. It is more commonly found as a hexahydrate, Co(NO3)2·6H2O, which is a red-brown deliquescent salt that is soluble in water and other polar solvents.
Uses
The high solubility of cobalt nitrate makes it a common source of cobalt in metal-organic frameworks and coordination chemistry. It is also reduced to metallic cobalt or precipitated on various substrates for Fischer-Tropsch catalysis.
Composition and structures of Cobalt nitrate
As well as the anhydrous compound Co(NO3)2, there are several hydrates of cobalt(II) nitrate. The various degrees of hydration can be summarised by the general chemical formula Co(NO3)2·nH2O, where n = 0, 2, 4, 6.
Anhydrous cobalt(II) nitrate adopts a three-dimensional polymeric network structure, with each cobalt(II) atom approximately octahedrally coordinated by six oxygen atoms, each from a different nitrate ion. Each nitrate ion coordinates to three cobalts.
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